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Stereochemistry in the Synthesis and Reaction of exo-Glycals.

✍ Scribed by Wen-Bin Yang; Yu-Ying Yang; Yu-Feng Gu; Shwu-Huey Wang; Che-Chien Chang; Chun-Hung Lin

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Synthesis of Furanosyl C-1 Glycals through Palladium-Catalyzed Reactions of a Furanosyl 2,3-Anhydro-exo-glycal
✍ Ana M. Gómez; Ana Pedregosa; Aitor Barrio; Serafín Valverde; J. Cristóbal López 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB 👁 1 views

## Abstract A furanose‐derived 2,3‐anhydro‐__exo__‐glycal, readily available from D‐mannose in four steps, has proven to be a useful substrate in the preparation of a variety of highly functionalized C‐1 glycals. Upon treatment with Pd^0^ it affords a π‐allyl palladium complex that can react with n