Stereochemistry from X-Ray Diffraction Studies of Three Palladium(II) Complexes with Terdentate Chelating Amines

✍ Scribed by Hattikudur Manohar; Dieter Schwarzenbach

• Publisher: John Wiley and Sons
• Year: 1974
• Tongue: German
• Weight: 186 KB
• Volume: 57
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19740570303

✦ Synopsis

Abstract

X‐ray crystal structure analysis of three Pd(II) complexes with cis‐3,5‐diaminopiperidine (DAPI) shows that the metal ion has a square planar coordination. The DAPI groups are trans in the protonated and mixed complexes. Most surprisingly, the unprotonated complex has a basket‐like structure with the DAPI groups cis.