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Stereochemistry and the use of H2/D2mixtures as probes into the mechanism of hydrogenations catalyzed by cationic rhodium (DIPHOS) complexes

✍ Scribed by S. -T. Lin; S. Siegel


Book ID
110170697
Publisher
Springer
Year
2006
Tongue
English
Weight
209 KB
Volume
47
Category
Article
ISSN
0023-1584

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The regioselective hydrogenation of some imines to the corresponding amines is efficiently catalyzed by [Ir(COD)(PPh 3 ) 2 ]PF 6 (1) and [Rh(COD)(PPh 3 ) 2 ]PF 6 (2) at 60 β€’ C and 200 psi of H 2 . The kinetics of the hydrogenation of N-(␀-naphthyl methylene) aniline (N␀NA) with [Ir(COD)(PPh 3 ) 2 ]P