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Stereochemistry and synthesis of precursors to strigol analogues

✍ Scribed by Gábor Tóth; Judit Halász; István Kádas; Géza Árvai; Katalin Mikló; Rainer Haessner


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
482 KB
Volume
33
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The relative configuration and conformation of the 8‐methyl‐5‐nitro‐1‐oxo‐Δ^8(8a)^‐octahydronaphthalene isomers were elucidated by various ^1^H and ^13^C NMR methods. The structure of the tricyclic by‐products was also determined.


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A complete and unambiguous assignment of the 1H and 13C NMR spectra of 5,5 2,5,5,9-tetramethyl-3,4-diazatricyclo [ 6.3.1.02,6 ]dodeca-3,9-diene-7,11-dione and 2, 5,5,12,12,9-hexamethyl-3,4,10,11-tetraazatetracyclo [ 1.3.6.6.02,6.09,13 ] undeca-3,11-diene-7,14-dione was accomplished by inverse two-d