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Stereochemistry and mechanism of the formation of 1,2-dimethylcyclopropane in the deamination of optically active 3-methyl-2-butylamine

✍ Scribed by Marc S. Silver; Allen G. Meek

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
216 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

Speculation continues on the role of protonated cyclopropanes, "free" or "hot" cations, 2-4 ion-pairs, et al. as intermediates in the deamination of primary aliphatic amines.

A belief that knowledge of the stereoselectivity characterizing the formation5 of trans-1,2dimethylcyclopropane 2) in the deamination of optically active 3-methyl-2-butylamine should provide insight into these questions prompted the experiments described below.

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