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Stereochemistry and Isotope Effects of the [2 + 2] Photocycloadditions of Arylalkenes to C 60 . A Stepwise Mechanism

โœ Scribed by Vassilikogiannakis, Georgios; Orfanopoulos, Michael


Book ID
127291673
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
138 KB
Volume
119
Category
Article
ISSN
0002-7863

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[2+2] photocycloadditions of cistrans-4-
โœ Georgios Vassilikogiannakis; Michael Orfanopoulos ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 198 KB

## The photocycloaddition of cis-and trans-1-(p-methoxyphenyl)-l-propene to C60 gives only the trans [2+2] adducts. Irradiation of the isolated adduct gives a mixture of cis-and trans-l-(pmethoxyphenyl)-l-propene and C60 cycloreversion products. These results exclude a concerted addition and are c