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Stereochemistry and chiroptical properties of the 3-phenyl-2-norbornanones

โœ Scribed by Thomas, Harold Todd.; Mislow, Kurt.


Book ID
126431096
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
915 KB
Volume
92
Category
Article
ISSN
0002-7863

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Stereochemistry and chiroptical spectra
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Several optically active substituted 3-azabicyclo[3.1.0]hexan-2-ones and their thiocarbonyl analogues have been synthesized, and their circular dichroism spectra studied. The crystal structure of thiolactam la showed that the bicyclic skeleton of the title compounds assumes a sofa-like geometry. It