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Stereochemical studies on esperamicins: Determination of the absolute configuration of isopropylamino sugar moiety

โœ Scribed by J. Golik; H. Wong; D.M. Vyas; T.W. Doyle


Book ID
104232877
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
201 KB
Volume
30
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The absolute stereochmistry of the isopropylamino sugar moiety of esperamicin A1 was determined as the g-&-threo-pentopyranosyl by comparing the CD spectra of derivatized methanolysis product 4 with those of two synthesized antipodal glycosides 2 and Is.


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