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Stereochemical Evidence Supporting the Intermediate-Mechanism of Dihalocarbene Addition

✍ Scribed by Prof. Dr. Eckehard V. Dehmlow; Dipl.-Chem. Roland Kramer


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
242 KB
Volume
23
Category
Article
ISSN
0044-8249

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large excess of ethanol at 75Β°C. k ( l a ) = 1.54 x lo-\*, k (1 b) = 1.06 x k ( I c ) = 4 . 7 7 ~1 0 -~, k ( l d ) = 1 . 8 3 ~1 0 -~. [6] The longest wavelength absorption band ofthiazolidine-2-thione appears at 280 nm, and the absorption coefficient is 13200. [71 Crystal data for 1 a at 296K: C,H,