## Abstract The isomeric tricyclo[4.4.1.1^2,5^]dodecanβ11βols have been synthesized from the (6+4) cycloaddition product of tropone with cyclopentadiene. The configuration and conformation of each isomer was determined from the proton shift gradients induced in the olefinic proton signals in the ^1
β¦ LIBER β¦
Stereochemical elucidation of isomeric tricyclic 1,4-benzodioxans (II) by the use of the NMR shift reagent, Eu(fod)3
β Scribed by James F. Caputo; Arnold R. Martin
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 154 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Recently the use of two new shift reagents, Eu(fod)3 and Pr(fod)3, have been reported by Rondeau and Sievers. * The advantage of these as shift reagents is due to their relatively high solubility in nonalcholic solvents and to the fact that neither Eu(fod)3
π SIMILAR VOLUMES
The configuration and conformation of th
β
Timothy J. Mason
π
Article
π
1981
π
John Wiley and Sons
π
English
β 275 KB
Assignment of relative configurations to
β
C. Alvarez Ibarra; M. L. Quiroga Feijoo; M. S. Arias Perez; J. de la Orden Parra
π
Article
π
1983
π
John Wiley and Sons
π
English
β 423 KB
An assignment of relative configurations has been achieved for the diastereomeric racernates(lR2R,lS2S) and (1R2S, 1S2R) of 3,3-dimethyl-l,2-diphenylbuta~-l-ol through the comparative analysis of the respective chemical shifts induced by Eu(fod), in the 'H and '"C NMR spectra, and the corresponding