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Stereochemical elucidation of isomeric tricyclic 1,4-benzodioxans (II) by the use of the NMR shift reagent, Eu(fod)3

✍ Scribed by James F. Caputo; Arnold R. Martin


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
154 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


Recently the use of two new shift reagents, Eu(fod)3 and Pr(fod)3, have been reported by Rondeau and Sievers. * The advantage of these as shift reagents is due to their relatively high solubility in nonalcholic solvents and to the fact that neither Eu(fod)3


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An assignment of relative configurations has been achieved for the diastereomeric racernates(lR2R,lS2S) and (1R2S, 1S2R) of 3,3-dimethyl-l,2-diphenylbuta~-l-ol through the comparative analysis of the respective chemical shifts induced by Eu(fod), in the 'H and '"C NMR spectra, and the corresponding