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Stereochemical Effect of Trans / Cis Isomers on the Aqueous Solution Properties of Acid-Labile Thermoresponsive Polymers

✍ Scribed by Huang, Xiaonan; Du, Fusheng; Liang, Dehai; Lin, Shrong-Shi; Li, Zichen


Book ID
127150318
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
859 KB
Volume
41
Category
Article
ISSN
0024-9297

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Polyurethane elastomers have been made using 1,4-cyclohexane diisocyanate ( CHDI) ,1,4butanediol (BDO) and a 2000 M , polyether diol soft segment. The cisltrans isomer distribution of the CHDI was varied between 23% and 100% trans. This variation in isomer distribution had significant effects on the