Stereochemical Course of the Reaction between Thiocarbonyl Compounds and Oxiranes: Reaction with cis- and trans-2,3-Dimethyloxirane
β Scribed by Milen Blagoev; Anthony Linden; Heinz Heimgartner
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- German
- Weight
- 272 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract The reactions of 1,3βdioxolaneβ2βthione (**3**) with (__S__)β2βmethyloxirane ((__S__)β**1**) and with (__R__)β2βphenyloxirane ((__R__)β**2**) in the presence of SiO~2~ in anhydrous dichloroalkanes led to the optically active spirocyclic 1,3βoxathiolanes **8** with Me at C(7) and **9** w
It has been shown that some reactions of diazo compounds and thiocarbonyl compounds proceed faster in the presence of LiCIO, [7] (cf: [Sj).