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Stereochemical course of direct ring closures of complex homoallylic alcohols to substituted tetrahydrofurans

✍ Scribed by Mihelich, Edward D.; Hite, Gary A.


Book ID
120402502
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
261 KB
Volume
114
Category
Article
ISSN
0002-7863

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## Abstract A new synthesis of bromo‐ and iodomethyl‐substituted tetrahydrofurans has been devised. The sequence starts with the conversion of aryl‐functionalized bis(homoallylic) alcohols **1** into __N__‐alkenoxythiazole‐2(3__H__)‐thiones **6** or pyridine‐2(1__H__)‐thiones **7**. When photolyzed