Sunnnary: Singlet oxygen adds stereoselectively to 8-isopropylidenetricyclo[3.2.1.02y4]octane. The T-orbital distortion and the secondary orbital interaction are discussed in order to explain the observed stereoselectivity. Recently it has been reported by two groups 2,3 that singlet oxygen adds ste
β¦ LIBER β¦
Stereochemical course in the addition of singlet oxygen to vinylcyclopropane derivatives.
β Scribed by G. Rousseau; P. Le Perchec; J.M. Conia
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 224 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
We recently described the regioselective addition of singlet oxygen to l,l-dialkyl 2,2_dicyclopropylethylenes and reported a remarkably easy cyclopropyl hydrogen
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