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Stereochemical control of the ynamine-Claisen rearrangement

โœ Scribed by Bartlett, Paul A.; Hahne, William F.

Book ID
111933768
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
262 KB
Volume
44
Category
Article
ISSN
0022-3263

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Stereocontrolled synthesis of conjugated
Stereocontrolled synthesis of conjugated dienamides via the ynamine-claisen rearrangement with (arylthio)ynamine
โœ Takeshi Nakai; Hiroyuki Setoi; Yasuhide Kageyama ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

dienamides is described which relies upon the acid-catalyzed or therma ynamine-CZaisen rearrangement with readiZy accessible laryZthiolynamines. The Claisen rearrangement has found substantial utility in the methodology of synthetic organic chemistry.2) For example, the reaction of an allylic alcoho