Stereochemical configuration of poly(methyl α-(p-chlorobenzyl)acrylate) and poly(methyl α-(p-methoxybenzyl)acrylate) synthesized by radical polymerization
✍ Scribed by Roman, Julio San; Madruga, Enrique Lopez; Lavia, M. Angeles
- Book ID
- 125990719
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 518 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0024-9297
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📜 SIMILAR VOLUMES
Al~tract---Methyl a-p-chlorobenzylacrylate and methyl :t-p-methoxybenzylacrylate were synthesized from dimethylmalonate by well known organic reactions. Both monomers were polymerizcd by a free-radical mechanism in benzene and their ceiling temperaturc determined. Comparison of the ceiling temperatu
## Abstract The use of a bisaminooxy compound as initiator for nitroxide‐mediated radical polymerization (NMRP) of styrene or __n__‐butyl acrylate allows the synthesis of __α__,__ω__‐nitroxide‐capped polymers. At high temperatures and with the addition of acetic anhydride, it was found that these p