Stereochemical assignment of the meridional isomer of the trisbidentate chelate complex Ga(fox)3 (fox = 5-fluoro-8-hydroxyquinoline) by two-dimensional correlated NMR

Quantitative 2D EXSY and Dynamic 19F-NMR

Quantitative 2D EXSY and Dynamic 19F-NMR Studies of the Dynamic Behaviour of the Bidentate Chelate Complex Ga(fox)3 (fox = 5-fluoro-8-hydroxyquinoline)

✍ Marina Gromova; Olivier Jarjayes; Sylvain Hamman; Robert Nardin; Claude Béguin; 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB 👁 1 views

F NMR / EXSY / Kinetics of ligand exchange / Bailar and Ra ˆy-Dutt mechanisms The rates of intramolecular rearrangement of the meridional isomer of the metal tris-chelate complex [Ga(fox) 3 , fox = 5fluoro-8-hydroxyquinoline] in DMF solution were measured using 1D NMR line shape analysis and 2D EXS