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Stereochemical assignment of the C35-C39 Acyclic linkage in maitotoxin: completion of stereochemical determination of C15-C134

✍ Scribed by Makoto Sasaki; Nobuaki Matsumori; Michio Murata; Kazuo Tachibana; Takeshi Yasumoto


Book ID
103400754
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
275 KB
Volume
36
Category
Article
ISSN
0040-4039

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## Abstract Geminal ^15^Nο£Ώ^13^C coupling constants have been measured in a series of ^15^N‐enriched 1β€’phenylβ€’3,5β€’dialkyl‐substituted pyrazoles. The importance of the orientation of the nitrogen lone‐pair in determining the magnitude of ^2^__J__(^15^N^13^C) values is reflected in the enhanced coupli