Stereochemical Assignment of the C21–C38 Portion of the Desertomycin/Oasomycin Class of Natural Products by Using Universal NMR Databases: Prediction
✍ Scribed by Yoshihisa Kobayashi; Choon-Hong Tan; Yoshito Kishi
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 109 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0044-8249
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✦ Synopsis
Stereochemistry can be predicted: The stereoselective synthesis of the C21-C38 degradation product derived from oasomycins A and B has confirmed the stereochemistry predicted from a comparitive study of the NMR chemical shifts of the C21-C38 portion of the natural products with those obtained for its diastereomers.
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