## Abstract The photolysis of azocyclopentane in the presence of cyclopentaneβcarbon tetrachloride mixtures has been investigated in the gas phase. Product analysis data have been used to determine the Arrhenius parameters for the reactions The rate data for chlorine atom abstraction from CCl~4~
Stereochemical aspects of the reaction of dialkyl phosphates with amine in the presence of triphenylphospine and carbon tetrachloride
β Scribed by Janina Baraniak; Wojciech J. Stec
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 259 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The photolysis of azocyclohexane, carbon tetrachloride, and cyclohexane at 360 nm has been investigated over a wide temperature range. At moderate temperatures a chain reaction ensues from which the following approximate rate constants could be determined assuming 2CCl~3~. β C~2~Cl~6~,
The photolysis of carbon tetrachloride in the presence of a number of alkanes has been investigated in the gas phase. The products obtained from the photolysis experiments were those expected from a chain reaction in which trichloromethyl radicals abstract hydrogen atoms from the alkane. The data ha