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Stereochemical applications of mass spectrometry. II—Chemical ionization mass spectra of isomeric dicarboxylic acids and derivatives

✍ Scribed by Alex. G. Harrison; R. Krisha Mohan Rao Kallury

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
639 KB
Volume
15
Category
Article
ISSN
1076-5174

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✍ R. Srinivas; M. Vairamani; K. V. Siva Kumar; M. S. Rajeev; G. K. Viswanadha Rao 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 338 KB

The tetramethylsilane (TMS) chemical ionization (CI) mass spectra of some geometrical isomers of unsaturated dicarboxylic acids, esters and isomeric phthalic acids reveal explicit differences. The (@-acids show an abundant [ M + 73 -CH,I + ion whereas the (a-acids exhibit a strong [ M + 73 -H,OJ + i