𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereochemical analysis of constituents of essential oils and flavor compounds by enantioselective capillary gas chromatography

✍ Scribed by König, Wilfried A. ;Krebber, Ralph ;Evers, Petra ;Bruhn, Gabriele

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
348 KB
Volume
13
Category
Article
ISSN
0935-6304

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Modified cyclodextrins interact enantioselectively with a great variety of volatile chiral constituents of essential oils by forming diastereomeric inclusion complexes. Capillary gas chromatography is used for resolving the enantiomers of terpenoid hydrocarbons (camphene, α‐pinene, limonene, α‐phellandrene), carbonyl compounds (carvone, fenchone, menthone, isomenthone, piperitone, camphor, myrtenal), and alcohols (trifluoroacetylated β‐citronellol, myrtenol, trans‐pinocarveol, 1‐octen‐3‐ol, and underivatized linalool). The enantiomeric composition of some of these compounds in a variety of essential oils is investigated.

📜 SIMILAR VOLUMES

Analysis of essential oils by direct sam
Analysis of essential oils by direct sampling from plant secretory structures and capillary gas chromatography
✍ Bicchi, C. ;D' Amato, A. ;Frattini, C. ;Nano, G. M. ;Cappelletti, E. ;Caniato, R 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 454 KB 👁 1 views

It is of fundamental importance to know the true composition of the essential oil produced by the secretory structures of a plant, both from a biogenetic and a chemotaxonomic point of view. This paper considers a method which combines direct sampling with on-column CGC and studies the oils directly