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Stereo-controlled synthesis of γ,δ-unsaturated ketones by the Horner-Wittig reaction

✍ Scribed by Christopher A Cornish; Stuart Warren


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
163 KB
Volume
24
Category
Article
ISSN
0040-4039

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A Convenient Synthesis of γ,δ-Unsaturate
✍ van Vliet, Michiel C. A. ;Meuzelaar, Gerrit J. ;Bras, Jér??me ;Maat, Leendert ;S 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 751 KB

## Abstract γ,δ‐Unsaturated __N__‐formylenamines (5–7) were prepared in two steps from readily available γ,δ‐unsaturated alcohols. The alcohols were converted into the γ,δ‐unsaturated diformamides (__N__,__N__‐diformylamines, 1–4) by tosylation, followed by reaction with sodium diformamide. The γ,δ