๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Stereo- and regiospecific syntheses to provide conjugated (E,Z)- and (Z,Z)-alkadienes, and arylated (Z)-alkenes in excellent yields via the palladium-catalyzed cross-coupling reactions of (Z)-1-alkenylboronates with 1-bromoalkenes and aryl iodides

โœ Scribed by Norio Miyaura; Makoto Satoh; Akira Suzuki

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
240 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

STEREO-AND REGIOSPECIFIC SYNTHESES TO PROVIDE CONJUGATED (E,Zl

-AND (Z,ZJ-ALKADIENES, AND ARYLATED (Z)-ALKENES IN EXCELLENT YIELDS VIA THE PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF (Z)-l-ALKENYLBORONATES WITH l-BROMOALKENES AND ARYL IODIDES

๐Ÿ“œ SIMILAR VOLUMES

A stereoselective route to alkenyl sulfi
A stereoselective route to alkenyl sulfides through the palladium-catalyzed cross-coupling reaction of 9-alkyl-BBN with 1-bromo-1-phenylthioethene or (E)- and (Z)-2-bromo-1-phenylthio-1-alkenes
โœ Yukio Hoshino; Tatsuo Ishiyama; Norio Miyaura; Akira Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

The reaction of 9-alkyl-9-BBNs with 1-bromo-i-phenylthioethene or (E)-and (Z)-2-bromo-lphenylthio-1-alkenes takes place readily in the presence of Pd(PPh& and sodium hydroxide to afford stereodefmed vinylic sulfides in excellent yields.