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Stepwise Synthesis, Structures, and Reactivity of Mono-, Di-, and Trimetallic Metal Complexes with a 6π + 6π Quinonoid Zwitterion †

✍ Scribed by Taquet, Jean-philippe; Siri, Olivier; Braunstein, Pierre; Welter, Richard


Book ID
121386800
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
294 KB
Volume
43
Category
Article
ISSN
0020-1669

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✍ Manfredo Hörner; Adailton João Bortoluzzi; Johannes Beck; Michael Serafin 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 102 KB 👁 2 views

The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ