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Stepwise synthesis of trimetallic dithiophosphinato clusters containing a cubane-type Mo2WCuS4 cluster core

✍ Scribed by Hansjörg Diller; Helmut Keck; Hartmut Wunderlich; Wilhelm Kuchen

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
376 KB
Volume
489
Category
Article
ISSN
0022-328X

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Isolation of a New Cs-Symmetrized Mo3(μ3-S)(μ-S)(μ-S2)2 Structural Type Through Complementary Association with a Cubane-Type Mo3NiS4 Cluster
✍ Rita Hernandez-Molina; Javier Gonzalez-Platas; Cristian Vicent 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 602 KB

A new cluster of formula {[Mo 3 (μ 3 -S)(μ-S)(μ-S 2 ) 2 (dtp) 3 (μ-OAc)][Mo 3 NiS 4 (dtp) 3 (μ-OAc)(CH 3 CN)]} (1; dtp = diethyl dithiophosphate; OAc = acetate) comprising the novel C s -symmetrized Mo 3 (μ 3 -S)(μ-S)(μ-S 2 ) 2 structural type covalently attached to a cubane-type Mo 3 NiS 4 core has