Stepwise solvation of molecules as studies by picosecond-jet spectroscopy: dynamics and spectra

✍ Scribed by Peter M. Felker; Ahmed H. Zewail

• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 617 KB
• Volume: 94
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(83)85031-3

✦ Synopsis

Rrwivtd 5 October 1962 \'c report WI Ihe stepwise sol~ted cm~plcxes of isoquinolinr with wa~cr. methanol, and acetone under supersonic jet cauditions. Lifetimes. dispersed fluorcswnce and excitation spectra are presented for different solute-solvenr complexes. ~111rsr studies rcvral maniicstations of solute-solvent hydrosen-bondins and of excited state hydrogen bond dissociation. * Gas phase dipole moments for methanol, water. and acetone have been measured as 1.7.1.85, and 2.88 D. respectively 191-Acknowledgement