Stepwise intramolecular vibrational-energy redistribution in the S1state of 3-amino and 3-amino-N-methylphthalimide molecules
โ Scribed by I. M. Gulis; A. I. Komyak; K. A. Saechnikov; V. A. Tsvirko
- Publisher
- Springer US
- Year
- 1993
- Tongue
- English
- Weight
- 371 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0021-9037
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Several theoretical methods are employed to characterize the intramolecular proton transfer in the ground state and in the lowest-lying 3 nฯ \* and 3 ฯฯ \* excited states of 1-amino-3-propenal. The geometrical parameters, the relative energy of the two tautomeric forms, the energy barrier for the pr
## Benzimidazole -and benzotriazole-amino derivatives of prog2enoic acid were studied by 'H NMR spectroscopy in the liquid state and by "C NMR spectroscopy in the liquid and solid states. The spectra shows tautomerism of the benzimidazole and benzotriazole rings, E-2 isomerism of the double bond o