Stepwise cycloadditions of pentadienyllithiums to 1,3-dienes
β Scribed by Newcomb, Martin; Ford, Warren T.
- Book ID
- 126418456
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 677 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Reaction of 1-indolylmagnesium iodidelo with the appropriate sulfonyldiene in benzene-ether (1: 1) at 0 "C resulted in a cycloaddition and after workup the teaahydrocarbazole product was isolated. Results from the reaction of a few 2-phenylsulfonyl 1,3-dienes are given in Table 1. In all cases only
## Abstract Arenediazonium ions 1 undergo [2^+^ + 4] cycloadditions with (__E__)β1,3βpentadiene (2a), 2,3βdimethylbutadiene (2b), and (__E__)β2βmethylβ1,3βpentadiene (2c) to give dihydropyridazines or pyridazinium salts. While highly electrophilic diazonium ions and the unsymmetrical dienes 2a and
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