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Stepwise cycloadditions of pentadienyllithiums to 1,3-dienes

✍ Scribed by Newcomb, Martin; Ford, Warren T.


Book ID
126418456
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
677 KB
Volume
39
Category
Article
ISSN
0022-3263

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## Abstract Arenediazonium ions 1 undergo [2^+^ + 4] cycloadditions with (__E__)‐1,3‐pentadiene (2a), 2,3‐dimethylbutadiene (2b), and (__E__)‐2‐methyl‐1,3‐pentadiene (2c) to give dihydropyridazines or pyridazinium salts. While highly electrophilic diazonium ions and the unsymmetrical dienes 2a and