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Stepwise Addition of MeS⊕ to a Metal-Carbon Triple Bond—A New Type of Reaction in the Chemistry of Carbyne Complexes

✍ Scribed by Priv.-Doz. Dr. Fritz R. Kreissl; Dipl.-Chem. Hans Keller

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 132 KB
Volume: 25
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198609041

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## Abstract Chromium alkoxy alkynyl Fischer carbene complexes react with symmetrical internal alkynes to form new and different organometallic species, which result from consecutive insertions of several alkyne units and carbonyl groups into the metal–carbon bond. The insertion sequence can be cont