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Stepped-up reactivity of a simple lanthanoid initiator. Polymerization of methyl methacrylate initiated with a lanthanoid alkoxide – ketene system

✍ Scribed by Hiroshi Sugimoto; Makoto Kato; Shohei Inoue

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 323 KB
Volume: 198
Category: Article
ISSN: 1022-1352
DOI: 10.1002/macp.1997.021980522

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✦ Synopsis

Abstract

Polymerization of MMA is achieved by using a novel initiator, most probably the lanthanum enolate growing species formed in the polymeritation of ketene with La(O^i^Pr)~3~. The design of this simple initiator is based on the stimulation of the reactivity of La(O^i^Pr)~3~, which by itself is inactive, upon the reaction with ketene.

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