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Steady-state electrolysis of an ampholyte solution and possibility of violation of the “law of pH monotony”

✍ Scribed by Alexander V. Stoyanov; Prof. Pier Giorgio Righetti

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
424 KB
Volume
19
Category
Article
ISSN
0173-0835

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✦ Synopsis

The problem of stationary electrolysis of a single-component ampholyte solution is analyzed. The effect of nonconstant relative mobility is taken into account. It is demonstrated that an incorrect dissociation model (i.e., expressing the resulting ampholyte flux by the arithmetic sum of the fluxes for "cationic" and "anionic" species) may lead to the violation of the so-called "law of pH monotony".

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