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Staudinger reaction in the series of 4-diazotetrahydrofuran-3-ones: Effect of substituents in the diazo and phosphine components

โœ Scribed by L. L. Rodina; S. V. Galiullina; N. V. Matyushina; V. A. Nikolaev

Book ID
111464559
Publisher
SP MAIK Nauka/Interperiodica
Year
2007
Tongue
English
Weight
179 KB
Volume
43
Category
Article
ISSN
1070-4280

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3-Diazo-3H-1,2,4\_triazoles convert to singlet 3H-1,2,4-triazol-3-ylidenes which ((effect directed i?lectrophilic substitutions of benzene?-and (2) coordinate with benzenoid substituents and nitro compounds to give decomposition or rearrangement products. Aromatic substitution by carbenes is importa