The unperturbed dimensions of poly-~-caprolactone (P~L), poly-t-propiolaetone (PilL) and polypivalolactone (PPL) have been evaluated theoretically. We find that the values of the characteristic ratio, Cยฎ, are 6" 66 (P~L), 3" 98 (P3L) and 8" 10 (PPL). The calculations are based, as usual, on the iso
โฆ LIBER โฆ
Statistics of Flexible Chain Configurations
โ Scribed by Frederick T. Wall, Frederic Mandel and John Chin
- Book ID
- 123655867
- Publisher
- National Academy of Sciences
- Year
- 1979
- Tongue
- English
- Weight
- 763 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0027-8424
- DOI
- 10.2307/69794
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The conformational energy of amylose molecule was computed a~ a function of rotations + and $ about interunit glycosidic bonds. The characteristic ratio (9 )&\ of &he mean-square end-to-end distance of the unperturbed chain to the product of n, the number of glucose residues in the chain and the squ