Statistical mechanics of electrolytes and polyelectrolytes. II. Counterion condensation on a line charge
β Scribed by Ramanathan, G. V.
- Book ID
- 121390124
- Publisher
- American Institute of Physics
- Year
- 1982
- Tongue
- English
- Weight
- 780 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.444322
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π SIMILAR VOLUMES
## Abstract It has recently been proven that the counterion condensate around an isolated line charge in an electrolyte, as characterized by nonlinear PoissonβBoltzmann theory, is an encapsulating Ξ΄βfunction. Here the identical result is shown to hold in the framework of the polyelectrolyte theory
## Synopsis A statistical mechanical derivation of the expressions for both pressure and ponderomotive force in a dielectric is given in terms of averages over microscopic quantities. The existence of microscopic long-range interactions leads to the possibility of defining pressure and ponderomoti