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Statistical mechanics of aliphatic chain layers, influence of chain-length mixing

โœ Scribed by Lemaire, B. ;Bothorel, P.

Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
438 KB
Volume
20
Category
Article
ISSN
0098-1273

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โœฆ Synopsis

Abstract

A molecular model is used to simulate interfaces composed of surfactants and cosurfactants in microemulsions where molecules are anchored at the surface of spherical micelles. A Monte Carlo calculation of the conformational properties of the aliphatic layer is carried out taking into account the rotational isomerism of the chains and the binary random distribution of chain lengths. The thermodynamic behavior and the main structural features of the monolayer are analyzed in relation to some micellar properties.

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