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Statistical analysis of 13C and 15N NMR chemical shifts from GIAO/B3LYP/6-311 + + G** calculated absolute shieldings

✍ Scribed by Fernando Blanco; Ibon Alkorta; José Elguero


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
185 KB
Volume
45
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ^13^C and ^15^N absolute shieldings of 28 compounds have been calculated at the GIAO/B3LYP/6‐311 + + G** level to complete a collection of data already published. This has allowed us to devise new equations relating δ and σ for these nuclei based on 461 points (^13^C) and 70(72) points (^15^N). Copyright © 2007 John Wiley & Sons, Ltd.