We present in this work a high-resolution Fourier transform infrared study of the OH-bending vibrational band of 13CH3OH. We have investigated the 1070-1400 cm-1 spectral region at 0.002 cm-1 resolution using the modified Bomem DA3.002 Fourier transform spectrometer at the Steacie Institute for Mole
State selective laser photofragment spectroscopy of OH in the MPD of CH3OH in a molecular beam
β Scribed by R. Schmiedl; U. Meier; K.H. Welge
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 398 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The internal and recoil energy of OH from the IR MPD of CHsOH has been invesbgated under molecular-beam conditions by laser-induced fluorescence. The recoil energy has been obtained by Doppler spectroscopy_ A Boltzmann-type distribution is found for rotation in u" = 0 and translation with temperatures Trot = (630 f 60) and Tkin = (400 f 20) K.
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