State-selected ion/molecule reactions by the TESICO technique. XIV. Separation of two microscopic reaction mechanisms in the reaction CH3Cl+ + CH3Cl → CH4Cl+ + CH2Cl
✍ Scribed by Shinzo Suzuki; Inosuke Koyano
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 755 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0168-1176
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The line shapes of the Balmer lines (n= 3, 4) produced from the reaction between methylene chloride and metastable helium atom He (2 %) in a high vacuum chamber were analyzed, and the nascent translational energies were estimated from their Doppler broadening profiles. The fractions of available ene
Energy transfer processes between metastable atoms He(2 'S) and CHaCI, have been investigated by emission spectroscopy. Intense CH(,4+X), CH(B+X), CH(C+X) and CCI(A+X) emission bands and weak hydrogen Balmer lines were observed. Using the reference reaction He(2 'S)+CO, the formation rate constant o
A new, improved variant of the very low pressure reactor (VLPR) system with interchangeable discharge orifices was used for studying the compatibility of the chemical and physical processes occurring simultaneously. It is shown that the ratio of calculated and effective escape rate constants is a co
A mixture of methane and chlorine molecules in a helium carrier is expanded into a vacuum chamber using a pulsed valve. Polarized laser photolysis of Clz at 355 nm is used to produce Cl(\*P,,2) with a sharply peaked speed distribution and a known angular distribution. Methane molecules are excited i