We present three-dlmenslonal quantllm mezhamcal calculations of the product state distnbuuons rn the H + D, + HD + D reacloo The two-potential formahsm of the dutorted-wave Born approxunation 1s used with the dIstorted potential taken to be the potential between the atom and the molecule when they a
State-resolved energy and angular differential measurements of the product distribution in the rearrangement reaction H− + D2 → HD(υ′) + D−
✍ Scribed by M. Zimmer; F. Linder
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 356 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0009-2614
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We report quasiclassical-trajectory quadratic-smooth-sampling calculations of the product state distributions for H + D, + HD + D reaction with four values of the initial relative translational energy, 1.5, 1.6,2.25, and 2.4 eV, and with initial rotational quantum number sampled at 300 K. The result
Complete quantum state distributions for HD (u= 1) and HD(u=2) are obtained by photolyzing HI at 266 nm m the presence of D2 and detecting the nascent HD product via (2+ 1) resonance-enhanced multiphoton ionization (REMPI). Calibration against an effusive oven source ( d 1800 K) yields any necessary