𝔖 Bobbio Scriptorium
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Starting materials for surfactants and textile auxiliaries

✍ Scribed by A. Sh. Yusupov; Kh. I. Isaev; E. P. Buzitskova; É. S. Zabran

Book ID
104816935
Publisher
Springer US
Year
1979
Tongue
English
Weight
215 KB
Volume
11
Category
Article
ISSN
0015-0541

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Azidophosphanes: Attractive starting mat
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✍ Lothar Riesel; Robert Friebe; Anke Bergemann; Detlef/Sturm 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB

Azidophosphanes are versatile reactants in the Staudinger reaction. The azides Cl2PN3 (I), (Et2N)ClPN3 (2), and (Et2N)2PN3 (3) react with phosphanes to give the N-phosphanyl phosphazenes 4-10. (Et2N)P(N3), is oxidized by PhN, yielding (Et2N)P(N3),=NPh (1 I), which with PPh3 yields the di-and triphos