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Stark effect and spectral hole-burning: solvation of organic dyes in polymers

✍ Scribed by Eric Vauthey; Keith Holliday; Changjiang Wei; Alois Renn; Urs P. Wild


Book ID
107942846
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
966 KB
Volume
171
Category
Article
ISSN
0301-0104

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The electric field effect of spectral holes, in the S, +So absorption band of octaethylporphyrin (OEP), is studied in matrices with different dielectric constants, t. The analysis of the hole-contours shows that the Stark effect is linear and provides an average matrix-induced dipole moment, A&,,, w

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Persistent spectral hole burning spectroscopy is applied to evaluate the low-temperature relaxation around the dye molecules doped in several types of polymers. The doped dye is tetraphenylporphine, and the measured polymers are vinyl polymers and main chain aromatic polymers. The changes of microsc