Starfish saponins. Part 9. A novel 24-O-glycosidated steroid from the starfishHacelia attenuata
โ Scribed by L. Minale; C. Pizza; R. Riccio; F. Zollo
- Publisher
- Springer
- Year
- 1983
- Tongue
- English
- Weight
- 293 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1420-682X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A nom2 steroidal glycoside has been isolated from the starfish Protoreaster nodosus. The structure includes a 3B,5a,6B,8B,lScr,24S-hexahydroxysteroidal moiety and a sugar moiety [2-0-methyl-B-D-xylopyranosyl-(1 + 21-a-L-arabinofuranosyZ]which is glycosidicaZZy attached at C-24 of the aglycone.
In continuation of our work' on starfish saponins, we report the isolation of the hitherto unknown 17~-methyl-3S,6cc-dihydroxy-18-no~5~-cholesta-9(ll)-l3-dien-23-one (I) from the sapoge nin portion of Astropecten aurantiacus, and show that it is an artefact produced during acid hydrolysis. Compound