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Standard thermodynamics of transfer. I. Silver and silver salt electrodes in glycerol + water mixtures

✍ Scribed by Upendra Nath Dash; Banka Behari Das; Uttam Kumar Biswal; Tapodhan Panda


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
736 KB
Volume
89
Category
Article
ISSN
0040-6031

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The standard potentials of the Ag/AgCl electrode in water-methylcellosolve mixtures have been determined at 25, 30,35,40 and 45°C. The values of E,,,' in each solvent is determined as a function of temperature. The plot of E,,,' against the reciprocal dielectric constant at 25°C indicates the existe