Standard molar enthalpies of formation ofNi(CH3COO)2,Ni(CH3COO)2·4.00 H2O,Cd(CH3COO)2, andCd(CH3COO)2·2.00 H2Oin the crystalline state
✍ Scribed by Manuel A.V. Ribeiro da Silva; Luı́s M.N.B.F. Santos
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 117 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0021-9614
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The title compound and its potassium analog have been prepared from corresponding aqueous solutions of 9 T c 0 , at p H z 2 with SO2 as a reducing agent. An X-ray structure determination of the Na-salt showed Tc coordinated to the tetradentate N (CH,COO)Z-ligand (NTA). Two Tc-NTA moieties are joined
Cu 2 (OH) 3 (CH 3 COO) • H 2 O can be prepared by slow titration of 0.1 M copper acetate solution with NaOH 0.1 M to a OH ؊ /Cu 2؉ ratio of 1 or by heating at 50(T(75°C copper acetate solutions with concentrations in the range 0.01 M4 [Cu 2؉ ] T 40.18 M. This species has been characterized by ab ini