Standard molar enthalpies of formation of triethoxymethane and tetraethoxymethane by rotating bomb calorimetry
✍ Scribed by K.N. Marsh; Margret Månsson
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 564 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0021-9614
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The standard enthalpies of formation of the following fluorinated b-diketones at T = 298.15 K were determined from their enthalpies of combustion measured using rotating bomb calorimetry.
The standard ( p o = 0.1 MPa) molar enthalpy of combustion of 4-iodobenzoic acid, at T = 298.15 K, was measured by static-bomb and rotating-bomb calorimetry, from which the standard molar enthalpy of formation, in the crystalline state, was derived. Rotating-bomb The values obtained confirm that 4
The standard (p°= 0.1 MPa) molar enthalpies of formation of crystalline 1,1,1-trifluoro-4-(2-thienyl)-4-hydroxy-3-buten-2-one, HTTFA, and 1,1,1-trifluoro-4-(2-thienyl)-4-mercapto-3buten-2-one, HTTFAS, at T = 298.15 K were measured by rotating-bomb calorimetry and the standard molar enthalpies of sub