Standard enthalpies of formation of gaseous dicyclopentadienyl-molybdenum and -tungsten dihyrides
✍ Scribed by Alberto R. Dias; Hermínio P. Diogo; Manuel E. Minas da Piedade; José A. Martinho Simões; Alexander S. Carson; Essam H. Jamea
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 492 KB
- Volume
- 391
- Category
- Article
- ISSN
- 0022-328X
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A high-temperature mass-spectrometric study of the vaporization of (silicon+boron nitride) from a boron-nitride Knudsen cell was conducted in the temperature range T = 1688 K to 1921 K. The partial pressures of Si(g), Si2(g), N2(g), and Si2N(g) were determined. The dissociation reaction: Si2N(g)=2Si
Standard enthalpies of combustion of phenanthrene and naphthacene were determined to be -(7048.7 ± 0.9) kJ • mol -1 and -(9005.1 ± 1.8) kJ • mol -1 , respectively, by means of high-precision micro-combustion calorimetry. The former result agrees very well with that reported by Steele et al. (AIChE S