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Stable Thiocarbonyl Ylides

✍ Scribed by Dr. Kazuhiro Nakasuji; Keitaro Nishino; Prof. Dr. Ichiro Murata; Dr. Hisanobu Ogoshi; Prof. Dr. Zen'ichi Yoshida


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
204 KB
Volume
16
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.


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Thiobenzophenone S-methylide (6) and 2,2,4,4-tetramethyl-3-thioxocyclobutanone S-methylide (17) were allowed to react with N-sulfinylaniline (7) and N-sulfinyltosylamide (8) furnishing 1,3,4-dithiazolidine 3-oxides. However, in the interaction 17 ‫ם‬ 8 the main product was the 1,2,4-oxadithiolane 2t