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Stable Rh2(MTPA)4 Phosphane Adducts − The First Example of P-Chirality Recognition by 103Rh NMR Spectroscopy

✍ Scribed by Damian Magiera; Wolfgang Baumann; Ivan S. Podkorytov; Jan Omelanczuk; Helmut Duddeck


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
122 KB
Volume
2002
Category
Article
ISSN
1434-1948

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Chiral phospholene and phospholane chalc
✍ Damian Magiera; Stefan Moeller; Zbigniew Drzazga; Zbigniew Pakulski; K. Michal P 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 243 KB

## Abstract Full NMR spectral assignments of the phospholene chalcogenides **1–12** are presented and their stereochemistry proven. The enantiomeric ratio of any of these compounds can be monitored easily by adding one mole equivalent of the chiral auxiliary Rh~2~[(__R__)‐MTPA]~4~ (MTPA‐H ≡ Mosher'