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Stable Platinum(0) Catalysts for Catalytic Hydrosilylation of Styrene and Synthesis of [Pt(Ar-bian)(η2-alkene)] Complexes

✍ Scribed by Jeroen W. Sprengers; Michiel de Greef; Marcel A. Duin; Cornelis J. Elsevier


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
155 KB
Volume
2003
Category
Article
ISSN
1434-1948

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## Abstract The platinum(0) complexes [Pt(C~2~H~4~)(PP)] (PP = 1,2‐bis[(diphenylphosphino)methyl]benzene (2) and (+)‐DIOP = (+)‐1,4‐bis(diphenylphosphino)‐1,4‐dideoxy‐2,3‐__O__‐isopropyliden‐D‐threitol), when promoted by CH~3~SO~3~H, become active catalysts for styrene hydroformylation with total y